Technical Paper Archive


This site contains all papers presented at Rubber Division, ACS Technical Meetings from 2000-2018. Meetings prior to 2000 are incomplete and papers are added as they are digitized.


For older papers not listed here, please send your request, including Meeting Year, Title, Author, and Paper # to: cbrady@rubber.org


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Silane-Terminated Liquid Poly(butadienes) in Tread Formulations: A Mechanistic Study

C18 henning silaneterminated liquid polybutadiene in tread formulations

Event: 196th Technical Meeting - Fall 2019
Location: Cleveland, OH
Date: October 08, 2019
Author: Steven Henning
Paper Number: C18

Price: $20.00

  • Liquid poly(butadienes) are materials which exhibit flow properties as their molecular weights are at or below that for significant chain entanglement. When applied to tire compound formulating in additive amounts, these low molecular weight oligomers are compatible with the elastomeric phase and can influence the viscoelastic behavior. The present paper will catalogue the history of the use of liquid poly(butadiene) materials in tire compounding, linking their varied application to the evolution of structure-property relationships as a function of microstructure changes. The result of this evolution is the commercialization of functionalized liquid polybutadienes, specifically silane-terminated grades designed for silica-filled systems. It has been found that these materials are not replacements for the typical silane coupling agents ubiquitously used in silica formulating, but rather synergistic with the established technology. The application of silane-terminated liquid poly(butadienes) can improve both traction indicators as well as limit the negative hysteresis effect commonly associated with the use of liquid poly(butadiene) resins. The mechanism behind the specific changes in viscoelastic and mechanical properties attributed to the addition of silane-terminated liquid poly(butadienes) is explored. It is found that the terminal silane function of the liquid poly(butadienes) may both interact with the silane coupling agent-modified surface of the dispersed silica particles as well as be available to intra-polycondense with each other, forming a higher molecular weight structure that may effectively increase apparent crosslink density and therefore bound rubber as an interpenetrating network that extends well into the elastomer phase.

    Papers from 196th Technical Meeting - Fall 2019

    Items from 196th Technical Meeting - Fall 2019