Technical Paper Archive

This site contains all papers presented at Rubber Division, ACS Technical Meetings from 2000-2018. Meetings prior to 2000 are incomplete and papers are added as they are digitized.

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Event: 174th Technical Meeting
Location: Louisville, KY
Date: October 14, 2008
Author: George A. Joyce*, William M. Henry and Ricky W. Magee
Paper Number: 92

Price: $20.00

  • The present work is a detailed investigation into the compression of carbon black using a new dynamic void volume analyzer (DVVA) with scanning capability. Prior research using a single- point equilibrium analyzer indicated compressed void volume (VV) is an improved structure measurement based on relationships to compound properties. This investigation indicates that within a manufacturing process, OAN can be accurately predicted from numerical models using differential void volumes. Universal OAN prediction models based on products from multiple producers were inaccurate due to variations in primary structure between producersi products. VV measurements obtained at high pressures and densities, where inter-aggregate void space is minimal, provides direct evidence that void volumes obtained from OAN testing are significantly over-estimated. Strong relationships observed between dynamic void volume and measures of compound processability and reinforcement confirms VV is an improved measurement of carbon black structure. The DVVA method is a faster analysis and more economical than OAN, uses a small sample mass, is non-dusting and self-cleaning resulting in significant advances in structure measurements of carbon black.

    Papers from 174th Technical Meeting

    Items from 174th Technical Meeting